In situ soft X - ray absorption spectroscopy investigation of electrochemical corrosion of copper in aqueous NaHCO 3 solution
نویسندگان
چکیده
A novel electrochemical setup has been developed for soft x-ray absorption studies of the electronic structure of electrode materials during electrochemical cycling. In this communication we illustrate the operation of the cell with a study of the corrosion behavior of copper in aqueous NaHCO3 solution via the electrochemically induced changes of its electronic structure. This development opens the
منابع مشابه
Investigation of corrosion protection properties of TiO2-CdO nanocomposite coating prepared by sol-gel method on copper
the Sol–gel nanocomposite coatings have been investigated for copper metal as a potential replacement for the hazardous and banned hexavalent chromate conversion coatings. TiO2–CdO nanocomposite thin films were deposited on copper using the sol–gel method. The sol-gel coatings were prepared using a sol obtained by the hydrolysis and condensation of tetra-o-butyl titanate. They were doped with c...
متن کاملCorrosion Protection of Copper by TiO2 Nanoparticles and SN Schiff base Coating
The corrosion protection abilities of modified copper in 2-[((Z)-1-{6- [(2-sulfanylphenyl)ethanimidoyl]-2-pyridyl}ethylidene) amino]-1- benzenthiol solution containing TiO2 nanoparticles were evaluated by Tafel polarization and impedance spectroscopy in 3.5% sodium chloride solution. The samples were characterized by energy dispersive X-ray (EDX) and scanning electron mi...
متن کاملCopper Corrosion in Aqueous Sulfide Solutions under Nuclear Waste Repository Conditions
The corrosion behavior of oxygen-free copper in anoxic sulfide solutions under nuclear waste disposal conditions was studied using electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) equipped with a focused ion beam (FIB), X-ray photoelectron spectroscopy (XPS) and Micro X-ray diffraction ( XRD). The film growth process and mechanism were elucidated using an Au mark...
متن کاملThe Effect of Simple Shear Extrusion on the Corrosion Behavior of Copper
In this study, corrosion behavior of copper that was deformed by Simple Shear Extrusion (SSE) method was investigated in 3%wt NaCl solution. Modified Williamson-Hall method, applied on the X-ray diffraction patterns of the samples, showed that increase in the number of SSE passes led to increasing in the dislocation density in the copper samples. Moreover, such deformed samples exh...
متن کاملCorrosion Behavior of a Fe-25at%Sn Supersaturated Solid Solution in H3PO4 Solution
Corrosion resistance of iron can be drastically improved by addition of passivating alloying elements. A supersaturated solid solution of Fe-25at%Sn was produced by mechanical alloying of commercially pure iron and tin powders for 24 hours using a planetary ball mill. Electrochemical measurements were performed on cold compacted unsintered specimens.. XRD investigation on produced alloy showed ...
متن کامل